A Review of the literature published between September and by K H Overton

By K H Overton

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C. Kokke and F. A. Varkevisser, J . Org. , 1974, 39, 1535. K. Hayashi, H. Nakamura, and H. Mitsuhashi, Chem. and Pharm. Bull. (Japan), 1973, 21, ‘‘I 2806. R. Calas, J. Dunogues, A. Ekouya, G . Merault, and N. Duffant, J. , 1974, 65, C4. J. I. Seeman and H. Ziffer, J. Org. , 1974, 39, 2444. I. D. Rae and A. M. Redwood, Austral. J. , 1974, 27, 1143. -Ficini has extended her stereospecific addition of an ynamine and an unsaturated ketone (Vol. 3, p. 39) to the rn-menthanes by using 5-methylcyclohex-2enone as substrate.

G. (114)], known to occur on gas ~ h r o m a t o g r a p h y , was ' ~ ~ not taken into account. '59 ' Nitration of p-cymene (117; R' = R 2 = H) has been known for well over a century to yield p-nitrotoluene by ips0 electrophilic attack (nitrodeisopropylation); now a novel mechanism, based on the idea of the C-1 position as that most active towards attack by nitronium ion, is supported by the isolation of up to 41 % of the ipso-adducts (1 18 ; cis and trans) and 41% of 2-nitrocymene (117; R' = H, R2 = NO,).

Eckell, and J. Meinwald, J . C . S . Perkin Z, 1973,2671. A. N. Blakitnyi, V. N. Boiko, E. V. Konovalov, Yu. A. Fialkov, and L. M. Yagupol'skii, Zhur. , 1974,10, 503; A. N. Blakitnyi, E. V. Konovalov, A. P. Sevast'yan, Yu. A. Fialkov, and L. M. , p. 509; cf: Vol. 2, p. 21. A. B. Booth, U S . P. 3 755 472. F. Yasuhara, Nippon Kagaku Kaishi, 1973, 1938. R. M. Carman and B. N. Venzke, Austral. J. , 1973, 26, 2235; 1974, 21, 383. R. M. Carman and B. N. Venzke, Austral. J. , 1974, 27, 441. R. M. Carman and B.

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